Single parameter
A one-parameter exponential family has the form
\[p(x \mid \theta) = \exp\{ s\theta - \psi(\theta) \} p_0(x),\]where
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$\theta$ is the natural parameter
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$s$ is the natural statistic
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$\psi(\theta)$ is the cumulant generating function
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$p_0$ is the base or reference distribution, although it need not be a proper distribution
Multiple parameter
All of these concepts extend in a straightforward way to the $d$-parameter exponential family:
\[p(x \mid \bt) = \exp\{ \s \tp \bt - \psi(\bt) \} p_0(x),\]where $\bt$ and $\s$ are now $d \times 1$ vectors.
Curved exponential family
Note that $d$ (the dimension of $\bt$ and $\s$) is not necessarily the same as the number of unknown parameters.
For example, suppose $x \sim \Normal(\mu, c^2 \mu^2)$, where $c$, the coefficient of variation, is known. The natural parameter and statistic are 2-dimensional, but there is only one unknown parameter. Note that $\bT$ is a one-dimensional parabola curving through $\real^2$.
Exponential dispersion family
A variation on exponential tilting, and one that is often very useful in statistical modeling, is to introduce a dispersion parameter and tilt by $\exp\lbrace \s \tp \bt / \phi \rbrace$. The resulting model is then of the form
\[p(x \mid \bt,\phi) = \exp \left\{ \frac{\s \tp \bt - \psi(\bt)}{\phi} \right\} p_0(x, \phi).\]This family of distributions is called the exponential dispersion family. Note that the normalizing constant is now $\exp\lbrace\psi(\bt)/\phi \rbrace$.